By Y. Marcus
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Extra info for 25th International Congress of Pure and Applied Chemistry. Plenary Lectures Presented at the 25th International Congress of Pure and Applied Chemistry, Jerusalem, Israel 6–11 July 1975
The critical event is a molecular collision between the molecules in the hot reacted gas, and the piston head of the transducer. In such a process, as hundreds of high school calculations show, there is a loss of energy, namely the translational (heat) energy is not all imparted LOAD ti Ï1 m s e «-O^R, Rn"*-0„*e u a W ELECTRON -SINK ELECTRODE SOLUTION ELECTRON -SOURCE ELECTRODE to the piston. Much of the energy which is given out in the reaction (the "Heat of Reaction") is lost. This is the origin of the Carnot efficiency difficulty of heat engines.
The details of this process of recrystallization are not yet known, but there is a gain in size of the particles concerned, so that the major factor is the so-called Ostwald ripening. Thus, the difficulty with lengthening the time at which a fuel cell electrode remains active is that one has to counteract a thermodynamic tendency. This does not imply exactly a pessimism in the task which concerns researchers in the practical abnegation of a ther modynamic trend. Doing that is a standard part of chemistry.
49 J. O'M. Bockris, Energy: The Solar-Hydrogen Alternative. Australia-New Zealand Book (1975). 50 R. D. Wittcofski, 1th Intersociety Energy Conf. San Diego (Sept. 1972). 51 J. V. Beeker, Astronautics and Aeronautics, 9 (8), 32 (1971). Pure & Appi. , Vol. 47, pp. 41-47. Pergamon Press, 1976. Printed in Great Britain. FIFTY YEARS OF QUANTUM CHEMISTRY E. , Cambridge, MA 02138, USA Abstract—An assessment of some aspects of the impact of quantum mechanics on chemistry will be attempted, with emphasis on the different ways it has had an important influence.
25th International Congress of Pure and Applied Chemistry. Plenary Lectures Presented at the 25th International Congress of Pure and Applied Chemistry, Jerusalem, Israel 6–11 July 1975 by Y. Marcus